Fluorescence maxima of 10-methylacridone-metal ion salt complexes: a convenient and quantitative measure of lewis acidity of metal ion salts.

نویسندگان

  • Shunichi Fukuzumi
  • Kei Ohkubo
چکیده

Aromatic carbonyl compounds such as 10-methylacridone form the Lewis acid complexes including paramagnetic and redox active Lewis acids. The fluorescence energies of the Lewis acid complexes are well correlated with the O2*--Lewis acid complexes derived from the gzz-values of the ESR spectra of the superoxide anion-Lewis acid complexes, thus providing a quantitative measure of the Lewis acidity.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 124 35  شماره 

صفحات  -

تاریخ انتشار 2002